Jimenez appeared to be knocked unconscious following a fifth-minute clash of heads with David Luiz and received oxygen on the field during almost 10 minutes of treatment before being taken to hospital.
Wolves hit the front through Pedro Neto and, although Gabriel briefly headed Arsenal level, the visitors claimed a deserved three points through Daniel Podence's superbly taken 42nd-minute winner.
The result moves Wolves up to sixth in the table, with Arsenal languishing in 14th.
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