French centre back Koundé opened the scoring in the 25th minute, dribbling from his own area and playing a one-two with a team mate before bursting past four Barça players to confidently slot past Marc-André ter Stegen.
Ronald Koeman suffered the cup exit when former player, Croatia midfielder Rakitic made sure of the victory with a thumping finish into the roof of the net in the 85th minute.
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