The Gunners host Eredivisie side at the Emirates stadium on Wednesday night.
The 22-year-old forward scored the first goal after 9 minutes when he pounced on a rebound from Martin Odegaard shot.
As at the time of this report, Arsenal are leading PSV 3-0.
Learndo Trossard scored the second before the Belgian provided the assist for Gabriel Jesus to have the third goal.
If you recall that Arsenal's previous involvement in the Champions League competition came in 2016-17.
Mikel Arteta guided thr Gunners back into the European competition after finishing second in the Premier League last season.
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