The Seleaco suffered defeat to Croatia after a penalty shoot out on Saturday evening.
Brazil took the lead after 105 when Neymar scored a thumping effort during the extra time.
But substitute Bruno Petkovic scored 116th-minute equaliser with Croatia's first shot on target.
The 28-year-old was seen crying after the penalty shoot out which saw the Brazil side miss two penalties while Croatia scoring all four.
The former Barcelona star didn't get a chance to play his own spot kick.
Neymar was seen being console by his team mate Dani Alves, 38-year-old who also made the cut.
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